منابع مشابه
Prediction of the material with highest known melting point from ab initio molecular dynamics calculations
Using electronic structure calculations, we conduct an extensive investigation into the Hf-Ta-C system, which includes the compounds that have the highest melting points known to date. We identify three major chemical factors that contribute to the high melting temperatures. Based on these factors, we propose a class of materials that may possess even higher melting temperatures and explore it ...
متن کاملInvestigating the highest melting temperature materials: A laser melting study of the TaC-HfC system
TaC, HfC and their solid solutions are promising candidate materials for thermal protection structures in hypersonic vehicles because of their very high melting temperatures (>4000 K) among other properties. The melting temperatures of slightly hypostoichiometric TaC, HfC and three solid solution compositions (Ta1-xHfxC, with x = 0.8, 0.5 and 0.2) have long been identified as the highest known....
متن کاملMelting Point Determination
An improved technique is described for the accurate determination of melting points of metals in the temperature range 1500° to 2500°C. The improvements consist of gradient heating and refinements in cavity preparation to obtain true black-body conditions. The melting point of hafnium, as determined by this method, is set a t 22220-+30°C. This is over 200°C higher than one of the values reporte...
متن کاملSolid clusters above the bulk melting point
The fact that the melting points of nanoparticles are always lower than those of the corresponding bulk material is a paradigm supported by extensive experimental data for a large number of systems and by numerous calculations. Here we demonstrate that tin cluster ions with 10-30 atoms remain solid at approximately 50 K above the melting point of bulk tin. This behavior is possibly related to t...
متن کاملHeat capacity of rare earth metals near the melting point and the vacancy mechanism of melting
The vacancy mechanism of the melting process is utilized as a starting point for deriving the formula for the difference of the heat capacity of the liquid and solid metal in the neighbourhood of the melting point. From these calculations it follows that the difference C,, C,, is the same for all the metals and equals 3.50 J g.atom-' K-'. This result is compared with the existing in the literat...
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ژورنال
عنوان ژورنال: Analytical and Bioanalytical Chemistry
سال: 2015
ISSN: 1618-2642,1618-2650
DOI: 10.1007/s00216-015-8564-y